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Vinyl Azides Synthesis Essay

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  • Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals. A New Synthesis of Chiral β-Iodo Azides, Vinyl Azides, and 2H-Azirines

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    Abstract | Full Text HTML | PDF | PDF w/ Links

  • Asymmetric Synthesis of 2H-Azirine 2-Carboxylate Esters

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  • Preparation of Novel Haloazide Equivalents by Iodine(III)-Promoted Oxidation of Halide Anions

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  • Azide and Cyanide Displacements via Hypervalent Silicate Intermediates.

    Eric D.Soli,Amy S.Manoso,Michael C.Patterson,PhilipDeShong,David A.Favor,RalphHirschmann, andAmos B.Smith, III.

    The Journal of Organic Chemistry199964 (17), 6526-6526

    Abstract | Full Text HTML | PDF | PDF w/ Links

  • Reaction of N-Vinylic Phosphazenes Derived from β-Amino Acids with Aldehydes. Azadiene-Mediated Synthesis of Dihydropyridines, Pyridines, and Polycyclic Nitrogen Derivatives

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    Abstract | Full Text HTML | PDF | PDF w/ Links

  • Molybdenum(IV) Complexes as Efficient, Lewis Acidic Catalysts for Allylic Substitution. Formation of C−C and C−N Bonds

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    Synthesis of vinyl azides

    Recent Literature

    A general silver-catalyzed hydroazidation of unactivated terminal alkynes with trimethylsilyl azide in the presence of water afforded the corresponding vinyl azides in good to excellent yields. This reaction has a broad substrate scope, good functional group tolerance, simple operation, and high reaction efficiency, thus providing an easy access to various functionalized vinyl azides.
    Z. Liu, P. Liao, X. Bi, Org. Lett., 2014, 16, 3668-3671.

    The nucleophilic addition of sodium azide to 1,2-allenyl esters regio- and stereoselectively generates vinyl azides in excellent yields. A sequential reaction for the synthesis of pyrroles using 1-allyllic 1,2-allenyl esters as substrates is developed on the basis of a domino process involving nucleophilic addition, cycloaddition, denitrogenation, and aromatization.
    X. Huang, R. Shen, T. Zhang, J. Org. Chem., 2007, 72, 1534-1537.

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